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Clean Air Sector Laboratory (CASLab)

Clean Air Sector Laboratory (CASLab), CASLab, Brunt Ice Shelf, Caird Coast

Position: Lat. 75°34'59"S, Long. 26°10'0"W

The Clean Air Sector Laboratory (CASLab) is a specialised observatory in coastal Antarctica dedicated to studies of this remote background atmosphere and the processes that influence its chemical signature. It contains a suite of instruments to measure the chemistry of the clean air and the snow surface around Halley.

The laboratory supports short-timescale studies to determine and quantify controlling processes, and long-term observations to monitor for compositional change.

Halley is a ‘Global’ station within the World Meteorological Organisation Global Atmospheric Watch Programme, providing critical baseline observations of atmospheric composition to the international community. Since 1983, Halley station has contributed to the NOAA cooperative sampling network.

The Halley CASLab is operated by the British Antarctic Survey but with a view to work collaboratively with research groups in the UK or international science community.

Location

The CASLab is located close to the Weddell Sea coast. As the coast effectively forms a promontory at this point, the CASLab is exposed to the Weddell Sea in three directions. The surrounding area is flat and snow-covered with the nearest rock outcrops roughly 200km away.

The CASLab sits approximately 30 metres above sea level on the floating Brunt Ice shelf in the Atlantic sector of coastal Antarctica.

The CASLab is situated 1km from the station generators, in a clean air sector that receives minimal contamination from the base.

Access to the laboratory is on foot or by ski. Vehicle access is limited to a few occasions each year for delivery of equipment.

Relocation

The CasLab was moved during the 2017-2018 field season as part of a three-year operational project to relocate Halley VI upstream of a previously dormant ice chasm that began to show signs of movement in 2012. The chasm could eventually cut the station off from the rest of the ice shelf.

Climate

During the summer months, an open water lead, that can be several tens of kilometres wide, extends along the ice front. During the winter, open water leads form regularly when the prevailing easterly winds force sea ice offshore.

In particular, Precious Bay, to the south-west of Halley, is normally ice-free during winter and spring such that air arriving at Halley from this direction (the secondary wind-rose maximum) is likely to have had contact with open water.

Wind speeds at Halley vary considerably through the year from very calm conditions to storms (mainly in winter/spring) gusting to 25 ms^-1. Annual temperatures range from just below 0°C in summer to around −45°C in winter.

Windspeeds and temperatures at the Clean Air Sector Laboratory (CASLab) (grey shading = polar night; yellow shading = polar day)

Annual light regime

At Halley, the sun stays permanently above the horizon from 2 November to 9 February and permanently below the horizon from 30 April to 13 August.

Before sun-up and after sun-down, scattered light can be observed at Halley for several hours around solar noon.

Technical information

The laboratory

The laboratory itself is constructed from three x 20ft shipping containers and mounted on a steel, legged platform. The platform is raised approximately every two years to maintain its height above the snow surface. This is necessary because of the amount of snow accumulation at Halley.

Floor plan of the CASLab: footprint is 20ft by 24ft (drawing not to scale)

Inlets

The CASLab has dedicated inlet stacks for trace gas and for aerosol sampling which are roughly eight metres above the snow surface.

Trace gas inlet stack

The trace gas inlet stack comprises a 100mm internal diameter (i.d.) electropolished stainless steel tube ventilated by a fan at the far end (see diagram below). The air flow through this central stack is ∼314 m³/hour, giving a residence time within the stack of less than 1 second. Samplers drawing from the stack remove only a small percentage of the total air flow. Access to the air flow is achieved via individual 1/4″ stainless steel tubing ports that penetrate to the centre of the air flow.

A cross section through the CASLab showing the main trace gas sampling stack. Trace gas analysers access ambient air through individual access ports along the length of the stack (drawing not to scale)

Aerosol inlet stack

The aerosol inlet stack comprises a 200 mm i.d. stainless steel chimney with a cowl at the air intake to prevent snow ingress (see diagram below). Ventilation is achieved using a fan with a variable flow rate. The flow rate can be altered according to the volume of air being drawn from the stack by samplers, thus enabling isokinetic sampling.

Each sampler accesses the stack via stainless steel cones installed at the base of the chimney (see Figs A and B below). The area of each cone is specific to a particular sampler’s flow rate, thus maintaining isokinetic flow up to the point of sampling (see Fig A below). Samplers connect to the cones via swagelock connectors.

Details of the air intake and sampling set up for the aerosol stack within the CASLab (drawing not to scale)

Gland plates

There are various locations in the walls and ceiling of the laboratory where gland plates allow penetration to the outside world. For equipment that cannot sample from the inlet stacks, dedicated inlets can be passed through the laboratory structure to equipment inside.

Power supply

Electricity in the CASLab runs at 240V, but a second circuit is available at 110V.

Compressed gas cylinders

There are two gas stores on the CASLab, one for flammable and one for non-flammable gases. A comprehensive gas distribution system exists for delivering gases to instruments in the laboratory.

Aerosol sampling

The CASLab is equipped with both high-volume and low-volume aerosol sampling equipment as well as a cascade impactor. Filter changes are done in a clean area of the lab under a laminar flow hood.

Instrument storage

There is space in the laboratory for instruments to be either rack-mounted or bench-mounted.

Wet chemistry

There is no running water at the CASLab, but any associated wet chemistry can be carried out at the wet chemistry laboratory on the main station platform. A supply of MilliQ water is available in the wet chemistry lab. Any solutions required for instrumentation can be brought to the CASLab on a sledge.

History

The CASLab was commissioned in 2003 at Halley V station (75°35′S, 26°34′W).It operated successfully for five years before a temporary suspension during the construction of the new Halley VI station.

In January 2012, the CASLab was installed at its new location at Halley VI (75°35′S, 26°10′W). The new site is some 20km from Halley V, and has effectively identical environmental conditions.

Purpose

Primary goals for the laboratory include:

characterisation of coastal Antarctic atmospheric chemistry
studies of snow photochemistry and air/snow exchange
studies of atmospheric chemistry associated with the sea ice zone e.g. halogens, surface ozone and mercury depletion
studies of Southern Ocean air/sea exchange signals and processes
monitoring for regional and global trends (given the clean and uncomplicated background system)
deriving baseline signals to understand ice core data (because understanding today’s system gives a chance to model the past)

Snow photochemistry and air/snow exchange

Rather than being an inert medium, the polar snowpack is highly chemically active and, consequently, is a major source of reactive trace gases to the overlying boundary layer.

For NOx, the major precursor is nitrate impurities from which NO₂ (as the major product) and NO (as the minor) are generated via photolysis.

There is evidence for the photochemical production of many other reactive trace gases from snowpack impurities, including HCHO, CO, C₂H₂ and HONO. There is also extensive physical exchange of species such as HCHO and H₂O₂.

Critically, many of these emissions are either a direct or an indirect source of OH, so the snowpack effectively controls the oxidising capacity of the atmosphere.

While considerable progress in understanding and quantifying snow photochemistry and air/snow exchange has been made in recent years, there is still some way to go before reliable assessments of the wider implications can be made.

Jones, A.E., Weller, R., Wolff, E.W., Jacobi, H–W., Speciation and Rate of Photochemical NO and NO₂ Production in Antarctic Snow, Geophys. Res. Lett., 27, 3, 345–348, 2000

Field experiment investigating production of NO and NO2 from a block of Antarctic snow by comparing mixing ratios in i) ambient air, ii) snowblock interstitial air when exposed to sunlight, and iii) snowblock interstitial air when shaded. Data are averages of 1 minute measurements for each time period shown. (Jones, A.E., Weller, R., Wolff, E.W., Jacobi, H-W., Speciation and Rate of Photochemical NO and NO2 Production in Antarctic Snow, Geophys. Res. Lett., 27, 3, 345-348, 2000. Copyright 2000 American Geophysical Union. Reproduced/modified by permission of American Geophysical Union)

Atmospheric chemistry associated with the sea ice zone

Tropospheric ozone depletion events (ODEs) are well-known phenomena that are observed in both polar regions during spring. Surface ozone drops from background concentrations to below instrumental detection limits (of a few parts per billion by volume).

At coastal stations, concentrations can remain suppressed on the order of hours to days. Observations over the frozen Arctic Ocean have found surface ozone to be depleted for several weeks at a time.

No equivalent observations from the frozen Southern Ocean exist. Vertical profiling measurements have shown that the depletion can extend from the ground up to ∼2 km altitude.

Halogens

The ozone depletion is driven by halogens, with bromine compounds (Br/BrO) appearing to play an especially important role. The source of Br/BrO appears tightly linked with the sea ice zone, although the precise mechanism(s) for delivering halogens to the atmosphere are still under debate.

Mercury depletion

Enhanced reactive bromine emanating from the sea ice zone also causes major perturbations to the mercury cycle. Atmospheric gaseous elemental mercury is converted to more reactive forms that can then be deposition to the surrounding ecosystems.

While the biogeochemistry of mercury has predominantly been studied in the Arctic, such processes have also been reported from the Antarctic.

Year-round measurements of surface ozone at Halley, 2007. The blown-up section highlights the springtime period during which tropospheric ozone depletion events are observed. Data are presented as 1-hour averages

Studies of Southern Ocean air/sea exchange signals and processes

The Southern Ocean is an important CO₂ sink, estimated to presently take up ∼7% of global CO₂ emissions every year. It has been suggested that CO₂ uptake by the Southern Ocean has reduced in efficiency over the past few decades, as increased winds over the ocean have enhanced the natural carbon outgassing rate over that of anthropogenic CO₂ uptake. This work is controversial, and a primary constraint on more definitive conclusions is the dearth of atmospheric observations in the Southern Ocean.

A recent biogeochemical modelling study has suggested that Antarctic continental shelves are major, but as yet unaccounted for, sinks of atmospheric CO₂. They calculated that the CO₂sink of the Ross Sea, a major embayment within the Pacific Ocean sector, is equivalent to 27% of the entire Southern Ocean. Halley lies at the edge of the Weddell Sea, the other major embayment.

Air arrives at Halley with a variety of histories, including passage over the open ocean and the nearby Weddell Sea. Access to such air masses, together with the longevity of the station, makes Halley an ideal location from which to study Southern Ocean air/sea exchange.

Monitoring for regional and global trends

Since 1983, Halley station has contributed to the carbon cycle measurement program of the NOAA collaborative sampling network. Whole air samples are collected approximately weekly in glass flasks and returned to NOAA’s Global Monitoring Division in the US for analysis of various gases including CO₂, CH₄, CO, H₂, SF₆, N₂O, ¹³C/¹²C in CO₂, ¹⁸O/¹⁶O in CO₂.

Example time series for CO₂ (Conway et al., 2011) and CH₄ (Dlugokencky et al., 2011) are shown below. Data shown in orange are preliminary. All other data have undergone rigorous quality assurance.

Conway, T.J., P.M. Lang, and K.A. Masarie (2011), Atmospheric Carbon Dioxide Dry Air Mole Fractions from the NOAA ESRL Carbon Cycle Cooperative Global Air Sampling Network, 1968-2010, Version: 2011-06-21

Dlugokencky, E.J., P.M. Lang, and K.A. Masarie (2011), Atmospheric Methane Dry Air Mole Fractions from the NOAA ESRL Carbon Cycle Cooperative Global Air Sampling Network, 1983-2010, Version: 2011-08-11

Deriving baseline signals to understand ice core data

A key to understanding the chemical development of our atmosphere is through study of changing chemical signatures in ice cores. They hold information on the state and composition of the atmosphere in the past, and hence how and why it has evolved.

The way to access this information is to find constituents that might be used as proxies for environmental changes in the past, but in order to do so it is necessary to understand the processes that created the ice core record. Such factors might include:

the nature of the sources
subsequent chemical reaction
transport to the deposition site
a range of deposition processes (in-cloud, below cloud, dry deposition)
post-depositional losses and movement

A proper understanding of the relationship between the chemical climatology of the atmospheric boundary layer and the chemical constituents in firn and ice is crucial for the correct interpretation of the cores that are used in palaeo-atmospheric reconstruction. In essence, we cannot hope to correctly reconstruct a past atmosphere if we do not properly understand that of the present day.

Data and plots

Following two successful year-round field campaigns, we have multi-seasonal measurements for the following atmospheric components:

NO/NO₂
CO
OH/HO₂
halogens (IO, BrO, Br₂, BrCl)
NMHC
HCHO
HNO₃/HNO₄
PAN/RONO₂
DMS
aerosol chemistry (filters)
2-pi spectroradiometer

On-going measurements include:

Component	Instrument
surface ozone BrO/IO Particle concentration Black carbon	TEI 49C Mini MAX-DOAS Condensation particle counter Aethalometer

Observations at the CASLab are supported by other measurements made at Halley, including standard and boundary layer meteorology, and total column ozone.

For access to these data, contact Anna Jones.

CASLab data publications

Jones, A. E., Anderson, P. S., Wolff, E. W., Turner, J., Rankin, A. M. and Colwell, S. R. 2006
A role for newly-forming sea ice in springtime polar tropospheric ozone loss? Observational evidence from Halley station, Antarctica
J. Geophys. Res., 111, D08306, doi:10.1029/2005JD006566.

Helmig, D., Oltmans, S., Carlson, D., Lamarque, J.-F., Jones, A. E., Labuschagne, C., Anlauf, K. and Hayden, K. 2007
A review of surface ozone in the polar regions
Atmos. Env., 41, 5138–5161, doi:10.1016/j.atmosenv.2006.09.053.

Anderson, P. S. and Bauguitte, S. J.-B. 2007
Behaviour of tracer diffusion in simple atmospheric boundary layer models
Atmos. Chem. Phys., 7, 5147–5158.

Read, K. A., Lewis, A. C., Salmon, R. A., Jones, A. E. and Bauguitte, S. 2007
OH and halogen atom influence on the variability of non-methane hydrocarbons in the Antarctic boundary layer
Tellus Ser. B-Chem. Phys. Meteorol., 59, 22–38.

Bloss, W. J., Lee, J. D., Heard, D. E., Salmon, R. A., Bauguitte, S. J.-B., Roscoe, H. K. and Jones, A. E. 2007
Observations of OH and HO2 radicals in coastal Antarctica
Atmos. Chem. Phys., 7, 4171–4185.

Mills, G. P., Sturges, W. T., Salmon, R. A., Bauguitte, S. J.-B., Read, K. A., and Bandy, B. J. 2007
Seasonal variation of peroxyacetylnitrate (PAN) in coastal Antarctica measured with a new instrument for the detection of sub-part per trillion mixing ratios of PAN
Atmos. Chem. Phys., 7, 4589–4599.

Saiz-Lopez, A., Mahajan, A. S., Salmon, R. A., Bauguitte, S. J.-B., Jones, A. E., Roscoe, H. K. and Plane, J. M. C. 2007
Boundary layer halogens in coastal Antarctica
Science 317: 348-351, doi: 10.1126/science.1141408.

Wolff, E. W., Hutterli, M. A., Jones, A. E. 2007
Past atmospheric composition and chemistry from ice cores — progress and prospects
Environ. Chem., 4, 211–216, doi:10.1071/EN07031.

Saiz-Lopez, A., Plane, J. M. C., Mahajan, A. S., Anderson, P. S., Bauguitte, S. J.-B., Jones, A. E., Roscoe, H. K., Salmon, R. A., Bloss, W. J., Lee, J. D., and Heard, D. E. 2008
On the vertical distribution of boundary layer halogens over coastal Antarctica: implications for O3, HOx, NOx and the Hg lifetime
Atmos. Chem. Phys., 8, 887–900.

Read, K. A., Lewis, A. C., Bauguitte, S., Rankin, A. M., Salmon, R. A., Wolff, E. W., Saiz-Lopez, A., Bloss, W. J., Heard, D. E., Lee, J. D., and Plane, J. M. C. 2008
DMS and MSA measurements in the Antarctic Boundary Layer: impact of BrO on MSA production
Atmos. Chem. Phys., 8, 2985–2997.

R. A. Salmon, S. J.-B. Bauguitte, W. Bloss, M. A. Hutterli, A. E. Jones, K. Read, and E. W. Wolff. 2008
Measurement and interpretation of gas phase formaldehyde concentrations obtained during the CHABLIS campaign in coastal Antarctica
Atmos. Chem. Phys., 8, 4085–4093.

Jones, A. E., Wolff, E. W., Salmon, R. A., Bauguitte, S. J.-B., Roscoe, H. K., Anderson, P. S., Ames, D., Clemitshaw, K. C., Fleming, Z. L., Bloss, W. J., Heard, D. E., Lee, J. D., Read, K. A., Hamer, P., Shallcross, D. E., Jackson, A. V., Walker, S. L., Lewis, A. C., Mills, G. P., Plane, J. M. C., Saiz-Lopez, A., Sturges, W. T., and Worton, D. R. 2008
Chemistry of the Antarctic Boundary Layer and the Interface with Snow: an overview of the CHABLIS campaign
Atmos. Chem. Phys., 8, 3789–3803.

Wolff, E., Jones, A. E., Bauguitte, S. J-B., and Salmon, R. A. 2008
The interpretation of spikes and trends in concentration of nitrate in polar ice cores, based on evidence from snow and atmospheric measurements
Atmos. Chem. Phys., 8, 5627–5634

Jones, A. E., Anderson, P. S., Begoin, M., Brough, N., Hutterli, M. A., Marshall, G., Richter, A., Roscoe, H. K., Wolff, E. W. 2009
BrO, blizzards, and drivers of polar tropospheric ozone depletion events
Atmos. Chem. Phys., 9, 4639–4652.

Pearce, D. A., Hughes, K. A., Lachlan-Cope, T., Harangozo, S. A., and Jones, A. E. 2010
Biodiversity of air-borne microorganisms at Halley station, Antarctica
Extremophiles, doi:10.1007/s00792-009-0293-8.

Jones, A. E., Anderson, P. S., Wolff, E. W., Roscoe, H. K., Marshall, G. J., Richter, A., Brough, N., Colwell, S. R. 2010
Vertical structure of Antarctic tropospheric ozone depletion events: Characteristics and broader implications
Atmos. Chem. Phys.,10, 7775–7794, doi:10.5194/acp-10-7775-2010.

Bloss, W. J., Camredon, M., Lee, J. D., Heard, D. E., Plane, J. M. C., Saiz-Lopez, A., Bauguitte, S. J.-B., Salmon, R. A., Jones, A. E. 2010
A Modelling Study of Radical Chemistry in the Antarctic Boundary Layer
Atmos. Chem. Phys., 10, 10187–10209.

S. J.-B. Bauguitte, N. Brough, M. M. Frey, A. E. Jones, D. J. Maxfield, H. K. Roscoe, M. C. Rose, and E. W. Wolff
A network of autonomous surface ozone monitors in Antarctica: technical description and first results
Atmos. Meas. Tech., 4, 645–658, 2011

Jones, A. E., Wolff, E. W., Ames, D., Bauguitte, S. J.-B., Clemitshaw, K. C., Fleming, Z., Mills, G. P., Saiz-Lopez, A., Salmon, R. A., Sturges, W. T. and Worton, D. R. 2011
The multi-seasonal NOy budget in coastal Antarctica and its link with surface snow and ice core nitrate: results from the CHABLIS campaign
Atmos. Chem. Phys., 11, 9271–9285, doi:10.5194/acp-11-9271-2011

S. J.-B. Bauguitte, W. J. Bloss, M. J. Evans, R. A. Salmon, P. S. Anderson, A. E. Jones, J. D. Lee, A. Saiz-Lopez, H. K. Roscoe, E. W. Wolff, and J. M. C. Plane
Summertime NO_x measurements during the CHABLIS campaign: can source and sink estimates unravel observed diurnal cycles?
Atmos. Chem. Phys., 12, 989–1002, doi:10.5194/acp-12-989-2012, 2012

Jones, A. E., Wolff, E. W., Brough, N., Bauguitte, S. J.-B., Weller, R., Yela, M., Navarro-Comas, M., Ochoa, H. A., and Theys, N.
The spatial scale of ozone depletion events derived from an autonomous surface ozone network in coastal Antarctica
Atmos. Chem. Phys.. Discuss., 12, 27555-27588, doi:10.5194/acpd-12-27555-2012, 201

Z. Buys, N. Brough, L. G. Huey, D. J. Tanner, R. von Glasow, and A. E. Jones
High temporal resolution Br₂, BrCl and BrO observations in coastal Antarctica
Atmos. Chem. Phys.., 13, 1329–1343, doi:10.5194/acp-13-1329-2013, 2013