Controls on the tropospheric oxidizing capacity during an idealized Dansgaard-Oeschger event, and their implications for the rapid rises in atmospheric methane during the last glacial period
The ice core record reveals large variations in the
concentration of atmospheric methane, [CH4], over the last
800 kyr. Amongst the most striking natural features are the
large, rapid rises in [CH4], of 100–200 ppbv, on timescales
of less than 100 years, at the beginning of Dansgaard-
Oeschger (D-O) events during the last glacial period (21–
110 kyr before present). Despite the potential insight they
could offer into the likelihood of future rapid rises in
[CH4], the relative roles of changes in methane sources and
sinks during D-O events have been little explored. Here, we
use a global atmospheric chemistry-transport model to
explore—for the first time, in a process-based fashion—
controls on the oxidizing capacity during an idealized D-O
event that features a characteristically rapid rise in [CH4]. We find that the two controls previously identified in the literature as having had significant (though opposing) influences on the oxidizing capacity between glacial and interglacial periods—changes in air temperature and emissions of nonmethane volatile organic compounds from vegetation—offset one another between idealized Heinrich stadial and Greenland interstadial states. The result is, the net change in oxidizing capacity is very small, implying the rapid rises in [CH4] at the beginning of D-O events were almost entirely source-driven. This poses a challenge to earthsystem
models—to generate a sufficiently large increase in
methane emissions in response to a simulated D-O event,
via a more realistic freshwater forcing impacting the strength
of the Atlantic meridional overturning circulation or, possibly,
other climate-change mechanisms. Citation: Levine,
J. G., E. W. Wolff, P. O. Hopcroft, and P. J. Valdes (2012),
Controls on the tropospheric oxidizing capacity during an idealized
Dansgaard-Oeschger event, and their implications for the
rapid rises in atmospheric methane during the last glacial period,